Showing posts with label Classification. Show all posts
Showing posts with label Classification. Show all posts

Screen printing



Screen printing:
Screen printing uses the principle of stencil. It is a resist method of printing in the sense that the screen is made to resist penetration of the print paste in areas where printing is not desired. Dye or pigment in a thickened formulation is forced by a blade or roller called a “squeeze” through a permeable screen onto a fabric under math the screen. Screen printing may be done with either flat or cylindrical screens.
Centuries ago, Japanese developed the stenciling technique for textile printing as a fine art, by the 19th century this printing method spreaded worldwide.
In 1850, French printers introduced the use of silk fabric to provide a continuous support for the paper stencil and that was stretched across a frame. This combination becomes known as a screen. At first screen fabric were made from hydrophilic yarn like cotton, silk, rayon etc afterward from hydrophobic ones like nylon and polyesters.
Strong developed mechanized screen printing process by the introduction of a movable carriage, in which the screens are mounted one at a time. The squeeze was driven by a motor attached to the carriage.
Fully automatic flat screen printing technique was developed by Buser, Stork and Johannes Zimmer in1950’s. These machines print all the colours in a design simultaneously along the top of an endless blanket conveyor belt.
Fully continuous printing by rotary screen was manufactured by AJC de O Barros in 1954. But this rotary screen had a seam line along its circumference.
The invention of seamless rotary screen of electrodeposited nickel was introduced by Zimmer in 1961 and latter by stork in 1963.
Machines using rod or roller squeeze manufactured by Zimmer was very successful in printing wider substrates e.g. carpets.
Currently rotary screen printing is the major printing method which replaced copper roller printing. These have also been used to print paper for transfer printing process.
Classification of screen printing:
There are four types of screen printing machines/processes-
1.      Hand screen printing.
2.      Semi-automatic screen printing.
3.      Fully automatic screen printing.
4.      Rotary screen printing.
Hand screen printing:
Hand screen printing is restricted in the college of art, small-scale unit and high fashion industries as it is a craft rather than a productive method of printing.
Here the number of color in a design is equal to the no. of screens used in that design. For every color, different print paste is made. Again in case of two or more color design the motif which covers more area in printed portion is applied first and so on. For hand screen printing the following things are required:-
        i.            Screen.
      ii.            Table
    iii.            Bed on the printing table.
    iv.            Back grey.
      v.            Fabric to be printed.
    vi.            Squeeze system.
As here the squeezer is manually driven by hand on the screen, it is called hand screen printing.
Printing is carried out on a flat, solid table covered with a large of resilient felt and a washable blanket (coated with neoprene rubber)
Fabric movement or shrinkage is avoided to maintain registration of the pattern. The fabric to be printed is laid on the table and stuck to be the blanket directly using either a water soluble adhesive. Alternatively the fabric is combined with a back-grey. In the latter  instance an absorbent fabric is stuck to the blanket and the fabric to be printed is pinned down on top of it, Sometimes fabric and back-grey are combined before fixing to the table using an adhesive and a special padding mangle.
Before printing the screens must be positioned carefully on the fabric. The area printed by a screen (screen repeat) must fit exactly alongside the adjacent one. Now print paste is taken on the screen. The printing process consists of forcing this viscous print paste through the open areas of the screen, with a flexible synthetic rubber squeeze. The rubber blade contained in a wooden or metal support is drawn steadily across the screen at a constant angle (about 45°) and pressure. Two strokes of squeezing gives better result. For very even print, 4 strokes are also done.
Advantages:
       I.            less investment cost.
    II.            Not so much necessity of dryer.
 III.            Multicolor design can be produced.
 IV.            Less floor space required.
    V.            Suitable for small scale production.
Disadvantages:
       I.            Slow production.
    II.            Small scale production.
 III.            Labour intensity is large.
 IV.            Fastness properties are not of international standard.
    V.            It is difficult to maintain even penetration of print paste through the screen.
 VI.            Not suitable for large scale production.
Controlling the amount of print paste passing:
1)      The ‘mesh’ (thread/inch) or ‘raster’ (threads/cm) of the screen fabric; generally a coarse mesh allows more paste to pass through than a fine one.
2)      The fraction of open area in the screen fabric, this depends not only on the mesh but also on the yarn diameter and the effect of subsequent treatments e.g. calendering.
3)      The hardness and the cross section of the squeeze blade; a hard rubber squeeze with a sharp cross section is suitable for outlines whereas a soft rounded blade applies more paste and is suitable for blotches.
4)      The hardness of the printing table. If the top of the table is firm a soft squeeze is suitable.
5)      The viscosity of the print paste, thinner paste passes through the screen more readily.
6)      The number of squeeze strokes generally 2-4 strokes are applied.
7)      The squeeze angle and pressure.
8)      The speed of squeeze strokes.
All these variables are taken into consideration along with the nature of design, when printing the chosen fabric.

Printing



Printing:
Printing is a process for applying color to a substrate. However, instead of colouring the whole substrate(cloth, carpet or yarn)  as in dyeing, printing colour is applied only to defined area to obtain the desired pattern. By the term “ Textile printing” we mean the localized application of dyes or pigments and chemicals by any method which can produce particular effect of colour on the fabric according to the design. This involves different technique and different machinery with respect to dyeing, but the physical and chemical processes that take place between the dye and the fiber are analogous to dyeing.
Step of printing:
Grey textiles/raw materials
Preparation of textile materials (singeing, desizing, scouring and bleaching)
Preparation of printing paste
Printing (with a certain style and method)
Drying of the printed fabric (in the drier)
Steaming of the printed fabric ( to transfer dye into fiber, 100-102, 15 min in a steamer)
After treatment (soaping of washing)

Steps of printing:
Ø  Color paste preparation: Generally the printing dyes or pigments are insoluble, during printing textiles, the dyes or pigments are not in an aqueous liquor instead, it usually finely dispersed in a printing past, in high concentration.
Ø  Printing: After suitable preparation of printing paste then it is applied to the substrate using different technique.
Ø  Fixation: After printing the printed textile material needed to fixation by dried. The prints are fixed mainly with steam or hot air.
Ø  After treatment: After fixation the specimen is needed to after treatment.
Printing paste and its ingredients:
Printing paste is viscous solution of printing ingredients referred below that is used for textile printing. The main three printing ingredient given below:
        i.            Dyestuff or pigments: Reactive, Disperse, Vat etc.
      ii.            Thickeners: Thickener can be defined as a substance used to increase the viscosity of a print paste or other fluid, which is controlled the disperse of dyes/pigments and contain the definite design.
    iii.            Chemicals and water: During printing many chemical is necessary such as wetting agents, reducing agents, oxidizing agents, dispersing agents, solvents, acids, alkalis, hygroscopic agents, catalyst and carries.
Printing pastes contain a thickening agent & other auxiliaries. According to their function, the classification given below:
        i.            Reducing agents(e.g. formaldehyde sulphoxylates, tin(‖)chloride, sodium dithionite, thiourea dioxide)
      ii.            Oxidizing agents(e.g. sodium chlorate, hydrogen peroxide, m-nitrobenzene sulphonate)
    iii.            Substances with a hydrotropic effect, like urea.
    iv.            For discharge printing, Discharging agents needed such as anthraquinone.
      v.            Resist for reactive resist printing such as sulphonated alkanes.
    vi.            Dye solubilisers, which are polar organic solvents like glycerine, butyl glycol, ethylene glycol etc.
  vii.            Defoamers( e.g. esterssilicon compounds etc)

Thickeners:
A thickener is a colorless, viscous paste made with one or more thickening agents.
Four significantly different approaches may be used to produced thickeners, using:
Ø  A low concentration of high relative molecular mass(r.m.m.).
Ø  A high concentration of a material of lower r.m.m. or highly branched chain structure.
Ø  An emulsion of two immiscible liquid, similar to the emulsions used as cosmetic creams or a foam of air in a liquid a dispersion of a finely divided solid.
Selection of thickener:
Ø  Viscosity
Ø  Print paste stability
Ø  Good adhesion of the dried thickener film
Ø  Minimum effect on color yield
Ø  Ease of removal
Ø  Acceptable cost
Important of viscosity:
There are two essential reasons for the importance of the viscosity and hence the flow, of a print paste.
First: It affects the amounts of paste applied.
Secondly: The spread of paste, on the surface of the textile material and into its structure.
The upper limit of the viscosity is determined by the flatness of the fabric surface and the condition of the printing process. The lower limit also depends on the process conditions, but is mainly determined sharpness of print.
Examples of natural thickeners:
1.      Starch and its derivatives(rice, potato, wheat etc):
                 i.            Provides high color yield
               ii.            Susceptibility to crush and poor levelness
2.      British gums:
                    i.            Good stability to alkali
                  ii.            Used for printing vat dyes
                iii.            For resist print, it is used
3.      Locust bean gum:
                    i.            Required 45 or higher for complete dispersion in water
                  ii.            PH has little effect on the viscosity over the pH range 3-11
4.      Guar gum:
                    i.            Can be dispersed in cold water.
5.      Alginates:
-          Source in brown phaeophycae seaweeds
-          Very important because of their ready solubility
-          Every after high temperature fixation treatments.
They are especially important for pastes of reactive dyes because the extent of interaction is very small.
The stability is good between pH 4 and 10.
 Alginate pastes are compatible with a wide range of materials, including starch and tragacanth.
6.      Gum Arabic:
Gum Arabic has been used as an adhesive more than as a thickening agent.
7.      Gum tragacanth:
It is less sensitive to additions of electrolyte.
Sequence of printing:
       I.            Printing with pigment:
Print   à  Dry   à   Curing(At 150 for 30s to 5 min)
    II.            Print with dye:
Print   à  Dry   à  Steaming/afeing(At 100-200 for 10s to 60 min)  à  After washing.
Style of printing:
Ø  Direct style
Ø  Discharge
White discharge
Color discharge
Ø  Resist style
Ø  Flock style
Ø  Crimp/Crepon style
Ø  Burn out style
Method of printing:
1)      Block printing
2)      Stencil printing
3)      Roller printing
4)      Screen printing
–Hand screen printing
–Semi automatic flat screen
–Rotary screen
5)      Transfer printing
–Flat bed
–Continuous transfer
–Vacuum transfer
6)      Digital inject printing

Pigments

Pigments:
Pigment is a substance in particulate form which is insoluble in water but which can be mechanically dispersed in this medium to modify its color and light scattering properties. They are organic or inorganic colouring materials.
Pigments have no direct affinity to textile fibers. They are fixed on textile materials (fabric/yarn) with the help of a binding agent in form of a this invisible coating.
In pigments auxochrome groups are absent. A number of organic pigments are prepared from dyes by combining the dyes with a dye precipitant.
Pigment are abundant in nature. The cause of color is not only the light absorption of molecules but also the purely physical effect of optical diffraction at grating systems. Pigments are applied at thickened pigment coating from oil-in-water or water-in-oil emulsion systems.
Properties of pigments:
        i.            It is insoluble in liquids but can be mechanically dispersed in the medium.
      ii.            Pigments have no direct affinity towards fiber, so binding is used as a binding agent in case of pigment colouration which sticks the pigment particle on the fiber surface.
    iii.            Pigment are applicable to all kinds of fibers.
    iv.            No aftertreatment is required after coloration process, only drying and curing are required.
      v.            Only rubbing fastness of pigment colouration is poor, but water wash and light fastness are very good.
    vi.            A wide range of bright shade can be produced by pigments.
  vii.            In pigments auxochrome groups are absent.

Differences between dyes and pigments:
The difference between dye and pigment is not a clear one. Most organic pigments are closely related to dyes with respect to their chemical structure. There are dyes which become pigments after application. Vat dye is a dye when used in dyeing, when vat dyes are oxidized and made insoluble in fabric(after vatting) that is called pigment form of vat dyes. Vat dyes act like pigment when used in printing. Now some differences are mentioned below:
1 ) The basic difference between dye and pigment is that, dye has three parts-
        i.            Chromophore, which is responsible for color.
      ii.            Auxochrome, which is responsible for dye properties
    iii.            Chromogen, which holds the above two together.
But pigment has two part:-
        i.            Chromophore, i.e. color bearing part.
      ii.            Chromogen.
2 ) Pigments are insoluble in the materials that they are used to color, whereas most dyes are soluble in them.
3 ) pigments are water insoluble, but dyes are more or less water soluble.
4 ) Pigments are used as colorants in the physical for in which they are manufactured. But dyes are first dissolved in water to form a dyebath, then they diffuse as single molecules from these solutions into textile fibers to colour them.
5 ) Pigments have no direct affinity towards textile fibers but most dyes have that.
6 ) Pigments are metallic compounds may be organic or inorganic. But dyes are mostly organic compounds, few are inorganic.
Classification of pigments:-
There are mainly two types of pigments, namely,
1.      Organic pigments and
2.      Inorganic pigments
Organic pigments are further classified as below:-
       I.            Dyes converted into pigments.
It has two types,
1) Dyes made insoluble by precipitating on substrates.
2) Vat dyes converted into pigments
    II.            ISO indolinone pigments
 III.            Azo pigments:
It has two types
1) Metal free{Water insoluble azo compounds (group1)}
2)Metal containing
    there are two types: chelates(group-3) and
Water soluble azo compounds(group-2)
–low soluble, make heavy metal salts(group-2a)
–high solubility precipitate heavy metal salts or basic substrates(group-2b)
 IV.            Quinacridone pigments
    V.            Phthalocyanine pigments

Inorganic pigments are classified by two types
       I.            White pigments and
    II.            Coloured pigments
There are three types of coloured pigments:
1.      Ultramarine
2.      Cadmium pigments and
3.      Iron oxide pigments.

Binder:
Binders are film forming polymers which play important roles in achieving optimum properties. Pigments have no affinity towards textile materials. So actually pigment particles are sticked on the surface of fabric. Binders are those adhesive type coating forming polymeric materials which sticks pigment particles on fiber/fabric surface. Binders are white, milk-like liquid. If forms a very thin invisible film on fabric surface during curing. Under this film pigment particles are remain sticked. So in pigment dyeing and printing binder is a very important and essential ingredient.
Binders with a particle size range of 0.05 to 2 microns are usually available. These contain about 6% by weight of reactive groups for crosslinking of the binder to textile. The reaction involved is as below:
Binder-CH2-OR + HO-textile = Binder-O-textile + HOR
[where Ris H or CH3 ]
Crosslinking increases the rubbing washing and drycleaning fastness properties, but it affects the handle of fabric.
Types of binder:
Binder can be classified according to many aspects, Some are mentioned below:
1.      According to origin: According to origin there are two types of binder,
                               I.            Natural binder- glue, gelatin etc.
                            II.            Synthetic binder- TROL, SLN, IG, Acramin binders etc.
2.      According to chemical groups: According to chemical group present in binder there are two types of binder, those are:-
                               I.            IG Binders: Emulsion copolymer of vinyl acetate and butyl acrylate with a modified urea formaldehyde.
                            II.            Ag Binders: They are made by emulsion copolymerization of olifinic unsaturated monomers in an aqueous medium. These monomers include:-
a)      Acrylic acid ester(butyl or ethyl acrylate)
b)      Styrene
c)      Acrylonitrile
d)     Vinyl chloride
e)      Asymmetric dichloroethane
f)       Vinyl acetate
g)      Diolifine such as butadiene
Required properties of a binder:
The binder must have certain qualities. For example:
        i.            It should not get coagulated due to shear forces.
      ii.            The binder film must be clear/transparent.
    iii.            The binder film must be of even thickness, smooth, neither too hard nor too soft.
    iv.            It should be elastic in nature and should have good adhesion to the substrate without being tacky.
      v.            It should have good resistance to chemical and mechanical stress.
    vi.            It should be easily removable from equipments.