Problem in dyeing with azoic color



1 ) Uneven shade:
The reason for uneven shade are :
        i.            Faulty liquor movement
      ii.            Faulty fabric movement during naphtholation
    iii.            Improper naphtholation
    iv.            Improper hydroextraction
2 ) Naphthol Migration:
The naphthol in fabric goes to base solution of the bath and reacts with base there other than in the fabric. This is called naphthol migration. This occurs due to:
            i.            Improper selection of naphthol
          ii.            More moisture in fabric
3 ) Slow coupling reaction:
The reasons for slow coupling reaction are:
            i.            Improper selection of base to mix with naphthol
          ii.            Wrong range of pH in bath, i.e. more acidity.
4 ) Affinity of base towards cellulose:
Azoic base should have affinity towards naphthol. But sometime it shows affinity towards cellulose. This hampers deing.
5 ) Blinding effect:
In case of rayon dyeing a blinding effect may occur, due to
              i.            Presence of alkali during naphtholation
            ii.            Improper value of pH
          iii.            Presence of alkali in coupling bath.
This blinding effect may be presented by using alkali binding agent (e.g. alum)
6 ) Pigment on fibre surface:
The reason for this are:
              i.            Unfixed dye on fibre surface
            ii.            Improper washing after dyeing
This can be prevented by:-
              i.            Using binding agent for alkali